The title reaction was theoretically investigated, where cis-[RhH(2)(PH(3))(3)](+) and cis-[RhH(2)(PH(3))(2)(H(2)O)](+) were adopted as models of the catalyst. The first step of the catalytic cycle is...
The carbonylation of methanol to acetic acid is a hugely important catalytic process, and there are considerable cost and environmental advantages if a process could be designed that was tolerant of h...
Dimeric rhodium(I) bis(carbonyl) chloride, [Rh(CO)(2)(mu-Cl)](2), is found to be a useful and convenient starting material for the syntheses of new cationic carbonyl complexes of both rhodium(I) and r...
PURPOSE: To determine the normalized glandular dose (DgN) for molybdenum target-rhodium filter (Mo-Rh) and rhodium target-rhodium filter (Rh-Rh) mammography and compare the average glandular doses (Dg...
Of the platinum group metal separations, that of rhodium from iridium is the most difficult. The existing gravimetric methods are too lengthy or make use of organic reagents which ultimately need to b...
Complexes [Rh(RF)(PMexPh3-x)3] (RF = CF3, x = 1 ( 2); RF = n-C3F7, x = 1 ( 3), x = 2 ( 4)) are quantitatively generated in situ when [Rh(-OH)(COD)]2 ( 1) is reacted with the corresponding Me3SiRF and ...
In aqueous solutions, as in organic solvents, rhodium hydrides display the chemistry of one of the three limiting forms, i.e. {Rh(I)+ H+}, {Rh(II)+ H.}, and {Rh(III)+ H-}. A number of intermediates an...