[reaction: see text] A new synthetic methodology is reported that takes advantage of the persistent free radical effect (PFRE), where clean products can be obtained in good yields from radical cross-c...
Detailed molecular orbital calculations were directed to the cyclopropylcarbinyl radical (1), the cyclopropoxy radical (2), and the cyclopropylaminium radical cation (3) as well as their ring-opened p...
Relationship between a radical species and radical acceptors of three different types of double bond in radical addition-cyclization was systematically investigated. Substrates carrying alpha,beta-uns...
Radical adducts of nitrosobenzene and 2-methyl-2-nitrosopropane with 12,13-epoxylinoleic acid radical, 12,13-epoxylinolenic acid radical and 14,15-epoxyarachidonic acid radical. Identification by h.p....
Pathways from chlorinated phenols as precursors to PCDD/Fs are discussed with focus on the effect of (poly)chlorination on thermochemistry and rate in the displacement of chlorine from a chlorophenol ...
Copper-catalyzed atom transfer radical polymerization (ATRP) is one of the most robust and precise techniques for controlling radical polymerization. The very good control of molecular weights, polydi...
The redox-active ligand 2-(3,5-dimethoxyanilino)-4,6-di- tert-butylphenol, H 2L (OCH3), results in, as expected, a trisradical complex with a low-spin Co(III) center, [Co (III)(L (OCH3) (*)) 3] ( 1), ...