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"
Borane
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- Catalytic dehydrocoupling of amine-borane and phosphine-borane adducts...
- The catalytic dehydrocoupling reactions of Me2NH.BH3 and Ph2PH.BH3 using the rhodium precatalyst [Rh(1,5-cod)(mu-Cl)]2 were found to proceed by different mechanisms: heterogeneous involving Rh(0) meta...
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Uploaded: 2004-2-5
- Heterogeneous or homogeneous catalysis? Mechanistic studies of the rho...
- In depth, comparative studies on the catalytic dehydrocoupling of the amine-borane adduct Me(2)NH.BH(3) (to form [Me(2)N-BH(2)](2)) and the phosphine-borane adduct Ph(2)PH.BH(3) (to form Ph(2)PH-BH(2)...
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Uploaded: 2004-8-5
- Ambiphilic diphosphine-borane ligands: metal-->borane interactions wit...
- Coordination of an ambiphilic diphosphine-borane (DPB) ligand to the RhCl(CO) fragment affords two isomeric complexes. According to X-ray diffraction analysis, each complex adopts a square-pyramidal g...
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Uploaded: 2007-10-20
- Synthesis and structural characterisation of a novel phosphine-borane-...
- The reaction between the phosphine-borane-substituted alkene [Pr(n)(2)P(BH(3))](Me(3)Si)C[double bond]CH(2) and elemental lithium in THF yields the complex [(pmdeta)Li[Pr(n)(2)P(BH(3))](Me(3)Si)CCH(2)...
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Uploaded: 2004-2-20
- Reactivity of vanadocene with a nitrile -C identical to N bond activat...
- Reaction of vanadocene [V(Cp)2] with "activated" nitrile R1CN.L (L: Lewis acid), obtained by the reaction of borane adducts (L = BR3; R = C6F5, 2,6-F2C6H3, 3,4,5-F3C6H2) with nitriles (CH3CN, F3CC6H4C...
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Uploaded: 2002-10-24
- 1-tert-butyl-2-methylphospholane-borane and its coupling product 2,2'-...
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Uploaded: 2000-7-21
- Synthesis, structure, and stability of adducts between phosphide and a...
- The phosphinoborane adduct H(3)P x B(C(6)F(5))(3) can be deprotonated using LiN(SiMe(3))(2) to give the phosphidoborate salt Li[H(2)PB(C(6)F(5))(3)], which was converted to the phosphidodiborates Li[H...
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Uploaded: 2009-10-30
- closo-borane conjugated regulatory peptides retain high biological aff...
- Despite the improvements in cancer therapy during the past years, high-grade gliomas and many other types of cancer are still extremely resistant to current forms of therapy. Boron neutron capture the...
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Uploaded: 2008-8-21