Group - Fluoroantimonic acid

 

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    Fluoroantimonic acid HSbF6 is a mixture of hydrogen fluoride and antimony pentafluoride in various ratios. The 1:1 combination affords the strongest known superacid, which has been demonstrated to protonate even hydrocarbons to afford carbocations and H2. The reaction of hydrogen fluoride (HF) and SbF5 is exothermic. HF releases its proton (H+), and its conjugate base (F-) is sequestered by one of more molecules SbF5 to give the octahedral SbF6-. This anion is classified as noncoordinating, because it is both a very weak nucleophile and a very weak base. The proton effectively becomes "naked", which accounts for the system's extreme acidity. Fluoroantimonic acid is 2×1019 (20 quintillion) times stronger than 100% sulfuric acid. The reaction of hydrofluoric acid and antimony pentafluoride proceeds as follows  



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