Shows both the reactions and properties of some chemical elements. Taken from the free online course...
Shows both the reactions and properties of some chemical elements. Taken from the free online course...
Freshman Organic Chemistry (CHEM 125) Professor Barry Sharpless of Scripps describes the Nobel prize...
Freshman Organic Chemistry (CHEM 125) Professor Barry Sharpless of Scripps describes the Nobel prize...
For the first time, researchers have prevented the typical age-related decline in a whole organ, all...
Oxidation/Reduction (cont.) (Prof. Catherine Drennan) View the complete course: ocw.mit.edu License:...
Oxidation/Reduction (Prof. Catherine Drennan) View the complete course: ocw.mit.edu License: Creativ...
Acid Base Titrations and Oxidation/Reduction (Prof. Catherine Drennan) View the complete course: ocw...
Chemistry 106 Spring 2008 Lecture 33 Professor Michael Kenney Schmitt Auditorium 4/16/2008 electro c...
Lecture 24: Balancing oxidation/reduction equations License: Creative Commons BY-NC-SA More informat...
In coordination chemistry, the oxidation number of a central...
DNA oxidation is the process of oxidative damage on Deoxyrib...
Omega oxidation is a process of fatty acid metabolism in som...
Oppenauer oxidation, named after Rupert Viktor Oppenauer Opp...
The Boyland-Sims oxidation is the chemical reaction of anili...
The Andrussov Oxidation is an organic reaction describing th...
The Rubottom oxidation is the chemical reaction of enolsilan...
Wet oxidation is a form of hydrothermal treatment. It is th...
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Date: (Publication Date: Apr 1971) Pages: () |
Abstract: Abstract An oxidation apparatus is described which continuously records the volume of oxygen absorbed by a sample of oil, in a closed system, maintained at constant temperature and pressure. The apparatus is automated through the use of a specially devised liquid level probe and other ancillary equipment such as recorders, timers, and temperature controllers. The apparatus can be used to compare the relative oxidation stability of various lubricants over a wide range of operating conditions.
In spite of the pathological significance of oxidation of plasma lipids, no method is currently available for the evaluation of the susceptibility of these lipids to oxidation in unfractionated plasma. Here we demonstrate that copper-induced oxidation of diluted plasma, in the presence of citrate can be monitored continuously by recording the absorbance at 245 nm. The kinetics of accumulation of oxidation products in unfractionated plasma is a sum of lipid oxidation products obtained in low and high density lipoproteins isolated from the same p...
The treatment of enrofloxacin synthetic wastewaters using conductive-diamond electrochemical oxidation (CDEO), ozonation and Fenton oxidation has been studied. Results show that the three technologies can reduce the organic content of enrofloxacin synthetic wastewaters but with different performances. CDEO was the most efficient technology in terms of mineralization but not on COD removal, which was more efficiently achieved by ozonation. This indicates that ozonation is efficient in the breakage of the complex molecules but not on the removal ...
In this paper, the application of Fenton and Oxone/Co(2+) oxidation processes for landfill leachate treatment was investigated. The removal of the chemical oxygen demand (COD), suspended substances (SS) and the color of the landfill leachate by Fenton oxidation to that by Oxone/Co(2+) oxidation were compared under optimal operational conditions. For Fenton oxidation process, the optimal conditions were determined as: [H(2)O(2)]=80 mmol L(-1), [H(2)O(2)]/[Fe(2+)]=2.0, initial pH=2.5, reaction temperature=37.5+/-1 degrees C, reaction time=160 min...
The stratum corneum is located at the interface between body and environment and thus is constantly exposed to a pro-oxidative environment. Previously, we have demonstrated that stratum corneum lipids are targets of oxidative stress induced by ozone and by ultraviolet A and B exposure. Here, we employed an immunoblotting technique to detect protein oxidation in human stratum corneum obtained by tape stripping. After lysis, protein carbonyl groups were measured by derivatization with dinitrophenylhydrazine, separation by sodium dodecylsulfate-po...
Immediately after birth, glycolysis and lactate oxidation are the major source of ATP production in the rabbit heart. Although the ability of heart to oxidize fatty acid increases within days, glucose oxidation rates remain low in the first week after birth. To further examine the changes in energy substrate use in the newborn period, we developed a right and left ventricular isolated working heart model, in which 2-wk-old rabbit hearts were perfused with buffer containing 11 mM glucose, 0.8 mM palmitate, 0.5 mM lactate, and 100 microU/mL insul...
We investigated the influence of glycated low density lipoprotein (LDL) for vascular smooth muscle cell (SMC) proliferation or injury. We utilized glycated, slightly oxidized LDL (GLDL-LOX), glycated, auto-oxidized LDL (GLDL) and glycated, metal-induced extensively oxidized LDL (GLDL-OX) to examine the effect of glycation itself or combined glycation and oxidation on SMC. GLDL-LOX induced SMC proliferation and migration, and increased the number of platelet-derived growth factor receptor, beta subunits, (PDGF-R) positive SMC. Also, GLDL-LOX pro...
The purpose of this study was to understand better the factors providing oxidation resistance to human low-density lipoprotein (LDL). Therefore, the susceptibility to copper-induced in vitro oxidation of LDL from vitamin E deficient patients and normal healthy subjects was studied. Surprisingly, the LDL of vitamin E deficient patients appeared less susceptible to oxidation than control LDL. Both oxidation rate and extent of oxidation, measured as diene production, were reduced when compared to control LDL. The lag time, a measure of resistance ...
Catalytic abatement of solutions of 1,000 mg/L in phenol, ortho and para nitrophenol and ortho and para cresols was acomplished by using two catalytic systems. Fenton's reagent was used at 50 degrees C by adding 10 mg/L of ferrous cation and different dosages of H2O2. The mixture was reacting isothermically in a batch way during 3 hours. Catalytic wet oxidation (CWO) was carried out by using a commercial Activated Carbon, Industrial React FE01606A, CWO runs were carried out in a fixed bed reactor (FBR) with concurrent upflow. Temperature and ox...
The susceptibility of carbon fibers and interphases to oxidation can prohibit the use of carbon fiber reinforced composites in applications with oxidizing environments at elevated temperatures. C/SiC composites and their constituents were studied in different tests in oxidizing environments to help identify the limitations of the basic C/SiC material system and point to potential protection schemes that can be used to inhibit oxidation of the carbon constituents. Thermogravimetric analysis (TGA) tests were conducted on C/SiC composites to study...
Reactions of peroxo-chromium(v) complexes with DNA afforded mainly guanine oxidation yielding, a four-electron oxidation product, guanidinohydantoin, and exhibited extensive base labile strand scission.
The susceptibility of carbon fibers and interphases to oxidation can prohibit the use of carbon fiber reinforced composites in applications with oxidizing environments at elevated temperatures. C/SiC composites and their constituents were studied in different tests in oxidizing environments to help identify the limitations of the basic C/SiC material system and point to potential protection schemes that can be used to inhibit oxidation of the carbon constituents. Thermogravimetric analysis (TGA) tests were conducted on C/SiC composites to study...
The susceptibility of carbon fibers and interphases to oxidation can prohibit the use of carbon fiber reinforced composites in applications with oxidizing environments at elevated temperatures. C/SiC composites and their constituents were studied in different tests in oxidizing environments to help identify the limitations of the basic C/SiC material system and point to potential protection schemes that can be used to inhibit oxidation of the carbon constituents. Thermogravimetric analysis (TGA) tests were conducted on C/SiC composites to study...